Diabetes: Diabetes can be caused by either the pancreas not producing enough insulin (Type 1 diabetes) or the body's cells not responding properly to insulin (Type 2 diabetes), or both. It is not directly caused by a deficiency of hormones but rather by an issue with the production or action of insulin, which is a hormone.

Goitre: Goitre can be caused by an iodine deficiency, leading to the thyroid gland's enlargement. The deficiency of iodine affects the production of thyroid hormones, which can result in goitre. Therefore, it is caused due to a deficiency of hormones.

Cancer: Cancer is not directly caused by the deficiency of hormones. It can have various causes, including genetic factors, environmental factors, lifestyle choices, and exposure to certain substances, but it is not primarily linked to hormone deficiencies.

Hypoglycemia: Hypoglycemia, or low blood sugar, can occur for various reasons, including excessive insulin, certain medications, alcohol, critical illnesses, or tumors. While some cases of hypoglycemia can be related to hormonal issues, it is not solely caused by a deficiency of hormones.

Based on the analysis, the condition not primarily caused due to the deficiency of hormones is:

1. Cancer.